Four Treasures Reference Database
Record No. 6256

Low-temperature heat treatment of pink sapphires from Ilakaka, Madagascar

Journal Article
Saeseaw, S., Khowpong, C. and Vertriest, W. (2020) Low-temperature heat treatment of pink sapphires from Ilakaka, Madagascar. Gems & Gemology, Vol. 56, No. 4, Winter, pp. 448–457.
ISBN/ISSN: 0016626X  |  DOI: https://dx.doi.org/10.5741/GEMS.56.4.448  |  RWHL*
Close Abstract Hide Keywords Copy Reference
gems, corundum, treatments.6, inclusions.5, Madagascar.12, pink sapphire
Rutile, titanium dioxide (TiO₂), is a tetragonal mineral that generally occurs in corundum as silk (exsolution-formed needles), dust-like exsolution particles, or macroscopic crystal inclusions. Rutile crystals can have orange to deep red-brown coloration, and the crystal shapes can be rounded or euhedral. The author recently examined a 4.24 ct faceted transparent blue sapphire from Afghanistan. The stone contained dusty flake-like inclusions, naturally healed fractures, lathe-like inclusions, twinning, rounded colorless crystals identified as apatite (RRUFF R040098), and an unusual long prismatic orange crystal identified as rutile (RRUFF R040049). This rutile crystal shape (figure 12) is not typical for corundum, particularly in blue sapphire.